Inorganic Chemistry

Why KMnO4 act as a good oxidizing agent in acidic medium?

In KMnO4, oxidation state of Mn is +7. As the oxidation state of atom increases, the element become more electronegative in nature. Mn gain 5 electron in acidic medium and reduces to +2 oxidation state.   Gain of 5 electron shows that the electronegativity of Mn has increased. Therefore, KMnO4 is a good oxidizing agent.   Note: […]

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What is the correct order of bond angle for O-P-X in the given molecules?

  Solution: Bond angle is inversely proportional to electronegativity of substituents.   i.e., Electronegativity of side atom increase then the bond angle (X-P-X) decreases.   So, X-P-X or F-P-F bond angle is least in POF3. That’s why the O-P-F is maximum.     Hence, the correct order of bond angle for O-P-X in the given molecules

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